This book describes a theoretical study involving endohedrally doped fullerenes and carbon nanotubes and substitutionally doped fullerenes using the first principle methods based on density functional theory. The effect on HOMO-LUMO gaps, charge redistribution, structural modification and modification of vibrational modes has been extensively studied by varying the number and type of dopant. It turns out that the findings of this work give direction on how to design these clusters with the help ...